I suspect she will be taken into the mind control fold in the current day Metrobay... but for us bondage freaks, we will be exploring the ordeals she endures during the 1940's and 1950's when R.O.P.E. was just a newly reorganized crime organization.
After the War, Metrobay became the gathering point for many fleeing fiends. We see the appearance of such villains as Black Hat, Frank Einstein, Vermillia and other assorted masked criminals. Valiant Woman and Ms Metrobay ( and another famous heroine) would face these demented villains and endure their brand of deviant wickedness.
Vith Tann, a cavewoman amazon at heart, fights alongside Ms Metrobay to fend off fiends. But truly, Valiant Woman is wild at heart and only truly cares about protecting her human female sisters. Her cavewoman origins still dominate her priorities, even in this modern world. Otherwise she sees men as little boys who need the guidance of women. She still looks upon men as the brutish apes of the human race.
Many a villain yearns to teach her a lesson.
When the radioactive meteor collided with Earth, Vith Tann was nearby and absorbed the full blast of the celestial impact. In the 1940s she is accidentally freed from her crystalline tomb and it's discovered that when she is in contact with the rare element from the radioactive metoer ( an element called Thslum) she exhibits incredible super stength, speed and flight ability. She can also focus her radioactive energy to project (or gift) her powers onto others. Without Thslum gem contact, her super powers seem to become dormant - she exhibits normal human capabilities.
A superheroine uniform was fashioned with a Thslum gem on her chest and on her headband so that she could harness her full superpowers.
Villains in the know...um, know...that if they can strip Valiant Woman of her body suit and headband she will be only another helpless damsel in their cruel clutches.
And so my fellow cartoon supervillains, here is our challenge to subduing this buxom beauty... and once we have stripped her of her Thslum gems we shall teach the uppity wench a proper lesson in obedience! Muuuuhahahahaha!
Um, okay, back to the drawing board